Vapour inhalation - LC50 - Propiconazole >5.8 mg/L air . Cyproconazole >5.6 mg/L air. May irritat nose and throat.
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -
23. TOXICITY SYMPTOMS:
No speciific symptoms.
24. FIRST AID:
If SWALLOWED - Rinse mouth with water. Give water to drink. If vomiting occurs then give more water and seek midical advice. Not harmful.
If in EYES - Irrigate for 15 minutes with plenty of water. Irritant. If irritation occurs seek medical advice.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water. Not harmful. Irritant. If irritation occurs seek medical advice.
If INHALED - Remove patient to fresh air. Not harmful
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote. No cases of human poisoning have been recorded.
Call Poisons Information Centre on 13 11 26
25. PROTECTIVE CLOTHING:
Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.
26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:
After spray has dried.
27. PROPERTIES:
Product appearance - Yellow to orange liquid with a sweet aroma.
Shelf Life -
Product Flammability - Flashpoint 63C. Not flammable. Not explosive. Combustible (C-1). Autoignition temp - 295C.
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - miscible with water.
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Vapour Pressure at 25 C. - Propiconazole 5.6x10-5 Pa. Cyproconizole 2.6x10-5 Pa.
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - SG = 1.08-1.2
pH 6.5 @ 1% aqueous dilution
Non corrosive. Not an oxidiser.
28. ENVIRONMENTAL FATE:
Summary - Toxic to aquatic life.
Birds - Cyproconazole - slight to moderate toxicity. Propoconazole - Practically non toxic.
Fish - Cyproconazole- slight;y toxic. Propoconazole - High toxicity LC50 >2.2-6.8 ppm.