Thiabendazole 200 plus Thiram 360
1. Trade Name 2. Manufacturer3. Formulation
FARMOZ FAIRGRO LIQUID FUNGICIDAL SEED DRESSINGFARMOZ PTY LIMITEDSC
OSPRAY REAPER TT LIQUID SEED DRESSING FUNGICIDEOSPRAY PTY LTDSC
P-PICKEL T LIQUID FUNGICIDAL SEED DRESSINGCROP CARE AUSTRALASIA PTY LTDSC

4. ACTIVE INGREDIENTS: Thiabendazole 200g/L + thiram 360g/L

5. COST: $50.05 per L or kg.

6. CHEMICAL GROUP: A,Y.

7. RELATED PESTICIDES:

Thiabendazole 200g/L + thiram 360g/L

8. GENERAL DESCRIPTION:

An agricultural fungicidal seed dressing combining two fungicides to provide contact, systemic, protective and curative action.

9. APPLICATION METHODS AND TIPS:

Applied as a seed treatment.

10. ADJUVANTS, WETTERS, OILS:

None recommended

11. EQUIPMENT:

Use equipment that provide even coverage.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Triple rinse with water and wetting agent. Clean equipment daily and don't allow mixture to dry out in equipment or flaking and blockages may occur.

13. WATER OR CARRIER DATA:

100 mL water per 200 mL product or 800 mL water per 200 mL product

14. WEATHER:

No specific effect.

15. RAINFASTNESS:

16. SOIL:

No specific effect.

17. PLANT HEALTH and OTHER EFFECTS:

May reduce to effectiveness of inoculum. Apply inoculum immediately before planting.

Seed may be used up to 15 months after treatment but effect on Pythium and Fusarium may be reduced.

Does not affect germination.

Use seed in the same season as it is treated.

Label states - don't feed treated seed to animals or poultry.

18. WITHHOLDING PERIODS:

Not required when used as directed.

Don't feed treated seed to stockor poultry.

Not required when used as directed.

Don't feed treated seed to stockor poultry.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

None required.

20. MODE OF ACTION:

Thiram - group Y, dithiocarbamate, multi site, contact and protective action.

Thiabendazole - group A, benzimidazole, sytemic, protective and curative action.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S6

Summary: Not particularly toxic but long term repeated exposure should be avoided.

Details:

Poison schedule - S6

Mammalian toxicity -

Acute oral LD50 - Thiram 560-1278 mg/kg (rats). Thiabendazole 3100 mg/kg [For comparison table salt is 3000 mg/kg]

Acute dermal LD50 - Thiram > 2000 mg/kg (rabbit). Thiabendazole >2000 mg/kg

Skin - Thiram mild irritant. Skin sensitiser. Thiabendazole Non irritating or sensitising.

Eye - Thiram moderate irritant. Thiabendazole Non irritant.

Vapour inhalation - LC50 - Thiram > 4.42 mg/L air (rat).

Chronic oral toxicity NOEL - ppm for two years. Can cause liver and Central nervous system effects in animal studies.

Thiram was mutagenic and teratogenic in animal tests. Not carcinogenic.

Acceptable Daily Intake (ADI) - Thiram 0.004 mg/kg/day. Thiabendazole 0.3 mg/kg/day.

23. TOXICITY SYMPTOMS:

Nausea, vomiting, diarrhoea, abdominal pain, dizziness, palpitations. rapid pulse rate, difficulty in breathing, lowering of blood pressure, dermatitis of skin.

Ingestion of alcohol will make symptoms worse.

Irritates eyes and skin.

May cause sensitisation of skin.

May cause respiratory irritation.

24. FIRST AID:

If SWALLOWED - Rinse mouth with water. Give a glass of water to drink. If vomiting occurs give more water. Avoid giving alcohol.

If in EYES - Irrigate for 15 minutes with plenty of water.

If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water. If redness, swelling, irritation or blistering occurs see a doctor.

If INHALED - Remove patient to fresh air. Keep at rest. If patient turns blue (cyanosis) clear airways and give oxygen. Apply artificial respiration if berating stops and seek immediate medical advice.

If patient has symptoms or is concerned contact a doctor immediately.

Advice to doctor - Treat symptomatically.

Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.

Elbow length PVC gloves.

Cotton overalls and washable hat.

Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

None specified.

27. PROPERTIES:

Product appearance - Bright green, opaque, viscous liquid with virtually no odour.

Shelf Life -

Product Flammability - Non combustible. Will emit toxic fumes if residue is burnt after water evaporates.

Half life in water - days at pH5 and 35 C.

Water solubility at 25 C. - dispersible.

Oil solubility -

Octanol:Water ratio at 25 C. - Thiram LogPow 1.73. Thiabendazole LogPow 2.39.

Vapour Pressure at 25 C. -

Dissociation constant - pKa.

Melting point - C.

Boiling point -

Molecular weight -

Density - SG=1.13

Unstable under acid conditions.

28. ENVIRONMENTAL FATE:

Summary - Toxic to aquatic organisms.

Birds - Low toxicity. LD50 Thiram 673->2800 mg/kg. Thiabendazole>2250 mg/kg

Fish - High toxicity LC50 Thiram > 0.0445-0.128 mg/L. Thiabendazole ) 0.55-16 mg/L

Invertebrates - High toxicity. LC50 Thiram0.21 mg/L. Thiabendazole 0.81 mg/L

Bees - May be harmful.

It has a half life in soil of 0.5 days for Thiram and 33-120 days for Thiabendazole.

It has an EPA classification for soil mobility that ranges from

Ground water contamination

Accumulation in milk and tissues.

29. COMPATIBILITY:

See HerbiGuide for compatability with other herbicides, insecticides and fungicides.

See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See Herbiguide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - None.

Hazchem Code -

Packaging Group - 3

EPG -

UN Number - 3082

Worksafe Classification -

NOHSC - Hazardous.

32. References:

Crop Care (2002) P-Pickel T Label and MSDS

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 for more information.